Archive June | archaeometallurgy
Jun 27 2013

Slag analysis – Schlackologie

Bastian Asmus

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Slag samples of a medieval (12th century) copper smelting furnace.
Top left: #21, XPL. Under crossed polarisers the zinc sulphide can be seen as tiny dendrites within the glassy matrix. The other phases are willemite (wlm) and copper (Cu), which is usually asso ciated with the (Zn,Fe,Cu)S phase, an accompanying phase of copper matte at the Huneberg, from which it probably segregates upon solidification. Free iron oxides are seen as dark and much larger dendrites.
Top right: Another section of #21, under plain polarised light. It shows the abundant spinels, the iron oxides and copper inclusions. Most notably it shows the free baryte (brt) inclusion in the slag matrix.
Bottom left: #22, shows more free baryte (brt), together with a lead antimony matte. The long needles are a mixed iron and zinc oxides and are believed to be franklinite (frk?). #104, is rather more affected by corrosion than the other two samples. It shows mainly spinel (sp), free iron oxides and some willemite (wlm). Spinels are in the same order of magnitude than in the other samples.

The colloquial term Schlackologie is used by several German colleagues in the archaeometric sciences when it comes to the analysis and interpretation of mostly metallurgical slags. Literally it would translate to slagology. But why are slags investigated at all and what exactly is slag?

What are slags and what do they consist of?

Slags are by-products of metallurgical or pyro-technological processes and usually remain at the production site as waste product. For example metallurgical smelting slag is usually composed of five separate components:

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Jun 27 2013

High power LED microscope illumination

Bastian Asmus

[tab: Overview]
sam_3004Problem: Your microscope is fine working condition, the optics are flawless, but illumination is either dim, brightness is not adjustable or bulbs are hard to come by.

Soultion: Retrofit your microscope with a high Power LED microscope illumination and these issues are in the past. Suddenly light consuming microscopy methods such as for example polarising or dark-field microscopy cease to be a problem. The utilised LED CREE XM-L is easily powerful enough for these tasks. The LED is powered with a  maximum of  1600 mA. At core of the  illumination solution is a LED driver and dimmer that I have specifically designed for this task. You can even make videos without any problems.

Custom made LED adapters are used for fitting the LED to your microscope. Upon request we can also do the conversion.

[tab: Universal LED Controller]
Bild der Unterseite der LED Steuerung: Einstellung des Maximalstromes für die LED MikroskopbeleuchtungThe Universal LED Controller is able to drive and dim all prevalent LEDs. Brightness may be controlled continuously between 0 and 100 %. Especially the new and powerful LEDs require fine adjustment if they are used in the bright field. To this end the universal LED controller was fitted with switch reduce the maximum power to 160mA, and thus adjusting the brightness in the bright-field is possible with ease. Of course this range may also be set to a different level by the user.

Further the controller features a set of six pre programmed maximum ratings to be able to drive LEDs other than 10W LEDs such as the CREE XM-L, without danger of destroying them.

The controller uses a softstart, i.e. there are no flashes during turning on the LED.

 

[tab: technical data]

 LED Adapter

  • High Power LED illumination retrofit solution
  • custom turned and anodised aluminium heatsink
  • e.g. for Zeiss illuminator 467040 and Zeiss Illuminator 15
    • adapter for for Carl Zeiss Jena illuminators
    • adapter for Carl Zeiss Jena Jenaval, Jenamed,…
    • for PZO Biolar
    • Leitz Laborlux
    • Leitz Diavert Köhler illumination
    • JEOL Electron Microprobe
  • LED: CREE XM-L
  •  UV /IR / colour LEDs may also be driven

Controller

  • Coarse adjustment 0-100 % light output (0-1600mA)
  • Fine adjustment is preset to 0 and 10% light output, may be set by the user
  • Maximum current may be set to: 1600, 1200, 900, 700, 350, 160 or 50mA
  • constant colour throughout the whole range
  • LED reaches a maximum of 65ºC under maximum current
  • Aluminium die cast enclosure in black, light grey ot hammerite (grey)
  • DC in  4,5-12V
  • reverse voltage protection
  • works well as battery driven device
  • designed and made in Germany

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LED Universal Controller 1600 mA
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Order at info [at] archaeometallurgie dot de or use the contact form in the lower right corner.
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Jun 20 2013

Casting processes

Bastian Asmus

A very brief introduction to casting processes

The production and casting of metals is a very old trade and is known at least for the last 7000 years or so. Early evidence for mining can be found at Ai Bunar, Bulgaria and Rudna Glava, Serbia from 5000 BC onwards. Casting is a very efficient and cheap way to manufacture a desired good. This is especially true for metals. Casting processes can be discerned by the way a mould is produced. There are two possibilities: permanent moulds and lost moulds.
Lost moulds can be used only once. In order to retrieve the raw cast you have to destroy them. Permanent moulds can be used for multiple casts; they are usually made of two, three or more parts, to allow for the retrieval of the cast. Lost moulds require a pattern permanent moulds do not.

Moulding process should further be classified by the way the model or pattern is handled. There are lost models and permanent patterns. Generally patterns is the term for models used for sand-casting, whereas with the  lost-wax method it is often called a model. But as far as I can see, the English/American terminology is unfortunately rather ambiguous. This page is concerned primarily concerned with heritage casting processes, which is why modern processes are not discussed here, however I make use of modern terminology wherever feasible.

Lost moulds and lost models These are the most important lost mould processes with lost models:

  • lost wax process
  • traditional bell founding
  • traditional gun founding

In the literature lost moulds are often said to be moulds of the lost wax or cire perdu process. This is incorrect as sand moulds are also lost moulds, as are the others mentioned above. In brief, the lost wax process uses positive wax model which is being invested in a moulding material, then heated, upon which the melting wax produces the mould cavity. This requires an individual model per cast. Early bells were made like this. The English/American terminology in the humanities coined the term direct and indirect lost wax process. This addresses the means of making the wax model, i.e. if each wax model made individually from scratch, or if  the wax model in itself was replicated by more efficient means, e.g. from a mould.

Some time after the 12th century the use of the lost wax method for bell founding was replaced by a more wax-saving process, which we nowadays call traditional bell founding process. This uses a strickle board to make the bell model from fine clay, which is used to make the two-part mould. Before casting the false dell (clay bell model) is removed. A similar technology came to bear in the production of cannon and, again, slightly modified also for the production of vessels such as cauldrons.

Lost moulds and permanent patterns

The single most important method mentioned her should be casting in sand moulds, which re-uses its permanent patterns. Sand moulds on the contrary possess permanent patterns which are being reused every time a sand-mould is made. Casting in sand moulds cannot be traces back very far. The earliest mentioning of this technique in our hemisphere is probably Al Jazari aorund AD 1200 . Susan La Niece published an excellent article putting forward the scarce evidence we have for early sand casting . In central Europe the earliest evidence is tzo found in written sources of the 16th century . Suggestions put forward by Egg that Gregor Löffler had introduced sand casting to gun founding are without any substance and reveal a simplistic view of foundry processes by that author.

Moulding loam – an ingenious material

In general, a moulding material should meet the following requirements:

  • refractory
  • no shrinkage
  • gas-permeable
  • fine-grained
  • slight decay after casting (not relevant for older processes)

Since pure clay is too fat, i.e. it shows too much shrinkage in pure form, the clay must be made leaner. This is done with inorganic and organic materials, which is called temper or grog. Archaeologically proven and/or historically/ethnographically documented temper is e.g.: (quartz) Sand, crushed old forms, animal hair, horse manure and chaff. The clay acts as a binder for the inorganic, refractory ageing agents. Since these do not shrink during drying, the shrinkage of the moulding material can be adjusted via their proportion.

Organic tempers have a different function; they improve the plastic properties in the green state. Due to their fibrous shape, they reduce cracking during drying. They improve the gas permeability as they burn when firing the moulds. The moulding loam is/was produced by each foundryman himself/herself and can be produced with experience at any place where work is/was done. The raw materials are available everywhere.

Historical sources such as Theophilus Presbyter in the 12th century , Vanoccio Biringuccio  or Cellini  in the 16th century share their recipes with us. Also at Lazarus Ercker, the famous sampler and metallurgist of the 16th century, you can find some hints on how to use clay to produce refractory materials .

Dies, permanent moulds

You do not need a model, but you have to engrave a three-dimensional negative into the moulding material. You also want to be careful as to ensure that the cast can be retrieved from the mould halves. This seriously restricts the design of your object and at least for prehistoric times this moulding technique yielded far less complicated cast products than the lost wax process. They are also more labour intensive to manufacture. The advantage is the re-usability of these, and many objects can be cast without much effort once a mould is made. The materials for permanent moulds have to be refractory and hard-wearing, e.g. stone and metal.

References

Asmus, B. (2016). Theophilus und der Guss einer Bienenkorbglocke. Ein Experiment. Der Anschnitt, 68(1–2), 45–60.
Biringuccio, V. (1990). The pirotechnia of Vannoccio Biringuccio: a classic sixteenth-century treatise on metals and metallurgy / translated from the Italian with an introduction and notes of Cyril Stanley Smith and Martha Teach Gnudi. (C. S. Smith & M. Teach, Trans.). Dover Publications.
Theobald, W. (1984). Technik des Kunsthandwerks im zwölften Jahrhundert des Theophilus Presbyter. Diversarum artium schedula. VDI-Verl.
Niece, S. L. (2016). Sand casting in the Islamic World. In B. Armbruster, H. Eilbracht, O. Hahn, & O. Heinrsichs-Tamáska (Eds.), Verborgenes Wissen. Innovation und Transformation feinschmiedetechnischer Entwicklungen im diachronen Vergleic (p. 263—276). Edition Topoi. https://doi.org/10.17171/3-35-11
Egg, E. (1961). Der Tiroler Geschützguß : 1400 - 1600. https://katalog.ub.uni-freiburg.de/link?id=038664887
al-Jazari, I. al-Razzāz. (1974). The Book of knowledge of ingenious mechanical devices. Donald R. Hill (translator). D. Reidel.
Ercker, L. (1968). Das kleine Probierbuch von 1556 / Lazarus Ercker / bearbeitet und eingeleitet von Paul Reinhard Beierlein / herausgegeben von Heinrich Winkelmann. Vom Rammelsberge, und dessen Bergwerk, ein kurzer Bericht von 1565. Das Münzbuch von 1563. Das Münzbuch von 1563. Vereinigung d. Freunde von Kunst u. Kultur im Bergbau e.V.
Brepohl, E. (Ed.). (2005). Benvenuto Cellini. Traktate über die Goldschmiedekunst und die Bildhauerei. Böhlau Verlag.